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Pro-Set epoxy pushes the performance boundaries even further… just in time for the next America’s Cup

In the high-speed, high-stress world of the America’s Cup, keeping the beast in one piece is clearly a big challenge. Structural attachments that require an adhesive bond need a strong yet also toughened epoxy adhesive to transmit loads between components. Achieving both strength and toughness can be tricky. The Pro-Set ADV-176/276 super-toughened epoxy adhesive, from Wessex Resins and Adhesives, delivers just this.

‘It might be good to have a very strong bond but you don't want one which just lets go without any warning,’ says Ineos Team UK’s manufacturing manager Michel Marie.

Over the years, as resins have been developed to be tougher, they have also needed to be more flexible so they can withstand a certain amount of displacement without breaking the bond.

So how are these key properties achieved?
‘We refer to it as a super-toughened adhesive,’ explains David Johnson of Wessex Resins. ‘The formulation includes nitrile rubber toughening additives that limit crack propagation through a joint when it's highly loaded so you don't get catastrophic failure.

‘Without these toughening additives, crack propagation occurs a lot more readily and can lead to bond failures. The rubber particles in the bond create cavitation sites within the adhesive interface and, if a crack does develop, shear-band yielding occurs around the particles rather than shearing straight through the material. As a result a crack is contained within the bond line.’

But minimising and containing fractures is only part of the technical benefits. Temperature is another important factor.

‘The resin systems we use for assembling various pre-preg components cure at room temperatures,’ continues Marie. ‘They are used to attach the structure inside the hull shell for example, or to bond the deck to the hull so they are very important high-stress connections between the primary element of the structures.

Main picture: Pro-Set ADV-176/276 is a supertoughened epoxy adhesive. Nitrile rubber toughening additives limit crack propagation through highly loaded joints, greatly reducing the risk of a sudden catastrophic failure.
Below: Pro-Setʼs abilities to cure at room temperature and make blind bonds without accidental voids are crucial advantages for early adopters like Ineos Team UK

Pro-Set super-toughened adhesive epoxy system is a very good product that we really like because it prevents the formation of voids in the bond line. This epoxy allows good control of the viscosity, which in turn allows us to make blind bonds without accidental voids which is always the tricky part of the process. In order to achieve a good consistent bond you need a product that flows well and gets into all the areas. But a product with a low viscosity that might achieve this could run away from the key area. Striking the right balance between a product that will flow and one that isn’t so viscous that air bubbles get trapped in the bond line is a tricky one to achieve but the Pro- Set ADV-176/ADV-276 supertoughened epoxy adhesive system delivers just this.’

Pro-Set’s ability to achieve highstrength bonds at room temperatures is also key.

‘As with any modern composite structure there will be a post cure process at some stage to achieve the final high structural properties of the entire structure but what we're after with those resin systems is versatility throughout a full range of temperatures,’ continues Marie. ‘For example in the middle of winter when you glue things together you might not necessarily be in a warm environment. Those resin systems need to be hard at the end of the day or the next morning. So we require a lot from those materials.’

Shipping can also be a key factor when it comes to the temperatures at which materials are cured. This is yet another of the many details that need to be considered during the development of a bonding system.

‘Shipping carbon structures around the world in containers can produce a challenging set of conditions for modern composites,’ says Wessex Resins’ David Johnson. ‘During a trip, containers can act as humid ovens at times and they can reach 100°C inside. Then when the structure is on location, surface temperatures can easily reach up to about 80°C plus, so the material needs to have good thermal properties wherever it's being assembled.’

With the new America’s Cup cycle taking the technical challenge on to another level, those close to the design and construction of the new breed are in no doubt as to how the structural demands will increase once again this time around.

‘This is my ninth America’s Cup and the nature of the game is always to push a bit further with every cycle,’ says Marie. ‘The AC75 Class rule is very exciting because the design space is really open and there’s a lot of time spent at the engineering stage to cater for loads that are much higher than they were for the AC50.’

Having faith in structural materials is key and when it comes to Wessex Resins’ products, Marie is clear. ‘The boatbuilders like it, which is always important.’

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